Solidification of undercooled eutectic alloys containing a third element
Received 9 July 2008; received in revised form 8 November 2008; accepted 1 December 2008. published online 24 December 2008.
Abstract
A theoretical model for lamellar eutectic growth in undercooled eutectic alloy melts with a third element has been developed; it was assumed that no other phase forms. It is found that the tip radius of eutectic dendrite decreases with increasing content of the third element so as to diffuse away its enriched atoms ahead of the solidifying interface easily. A critical content exists below which the eutectic growth is accelerated within a certain undercooling range due to the third element addition, but slowed down otherwise. When more of the third element is contained, the growth velocity is always reduced. However, the eutectic lamellar spacing varies with the content in an opposite way. The influence of the third element addition is enhanced when the difference in distribution coefficients of the third element in two eutectic phases becomes greater.